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Copper(II) Sulfate Pentahydrate, Reagent ACS (Fine Crystals)
96003
**** SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ****
MSDS Name: Copper(II) Sulfate Pentahydrate, Reagent ACS (Fine Crystals)
Blue Vitriol
Company Identification: Acros Organics N.V.
One Reagent Lane
Fairlawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7758-99-8 |COPPER(II) SULFATE PENTAHYDRATE | | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 36/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Appearance: Not available.
Warning! Air sensitive. This substance has caused adverse
reproductive and fetal effects in animals. Harmful if swallowed.
Causes eye and skin irritation and possible burns. Causes digestive
and respiratory tract irritation with possible burns.
Target Organs: Blood, kidneys, liver, lungs.
Potential Health Effects
Eye:
Causes eye irritation. Causes redness and pain.
Skin:
Causes skin irritation.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea.
Inhalation:
Causes respiratory tract irritation.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Prolonged
or repeated eye contact may cause conjunctivitis. May cause liver and
kidney damage. May cause anemia and other blood cell abnormalities.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower lids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of soap and water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid. Induce vomiting by giving one teaspoon of Syrup of
Ipecac.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing,
give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Antidote:
The use of d-Penicillamine as a chelating agent should be determined
by qualified medical personnel.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Substance is noncombustible.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
Autoignition Temperature: Not available.
Flash Point: Not available.
NFPA Rating: Not published.
Explosion Limits, Lower: Not available.
Upper: Not available.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
+--------------------+-------------------+-------------------+-----------------+
| Chemical Name | ACGIH | NIOSH |OSHA - Final PELs|
|--------------------|-------------------|-------------------|-----------------|
| COPPER(II) SULFATE |fume: (0.2) mg/m3 |as Cu: 1 mg/m3 |fume, as Cu: 0.1 |
| PENTAHYDRATE |TWA; dusts and | TWA (dusts and | mg/m3 TWA; dust|
| | mists, as Cu: |mists); 0.1 mg/m3 |s and mists, as C|
| | (1) mg/m3 TWA |TWA (fume) |u: 1 mg/m3 TWA |
| |(listed under |(listed under | (listed unde|
| |COPPER). |COPPER).dusts as |r COPPER). |
| | | mists as Cu: 100 | |
| | |mg/m3 IDLH | |
| | |(listed under | |
| | |COPPER). | |
+--------------------+-------------------+-------------------+-----------------+
OSHA Vacated PELs:
COPPER(II) SULFATE PENTAHYDRATE:
fume, as Cu: 0.1 mg/m3 TWA (listed under COPPER
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133.
Skin:
Wear impervious gloves.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR
1910.134. Always use a NIOSH-approved respirator when
necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Appearance: Not available.
Odor: Odorless
pH: Not available.
Vapor Pressure: 7.3 mm Hg @25 deg C
Vapor Density: Not available.
Evaporation Rate: Negligible.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 110 deg C dec
Decomposition Temperature: Not available.
Solubility: slightly soluble in alcohol and glycerol
Specific Gravity/Density: Not available.
Molecular Formula: CuO4S.5H2O
Molecular Weight: 249.69
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, incompatible materials, exposure to air.
Incompatibilities with Other Materials:
Finely powdered metals, corrodes steel.
Hazardous Decomposition Products:
Oxides of sulfur, oxides of copper.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7758-99-8: GL8900000
LD50/LC50:
CAS# 7758-99-8: Oral, rat: LD50 = 300 mg/kg.
Carcinogenicity:
COPPER(II) SULFATE PENTAHYDRATE -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology:
No information available.
Teratogenicity:
Anhydrous: see Rtecs# GL8800000:
ivn-mouse TDLo=3200 ug/kg. Fertility: post-implantation mortality,
ivn-mouse TDLo=3200 ug/kg. Specific Developmental Abnormalities: body
wall, ivn-hamster TDLo=2130 ug/kg; cardiovascular and central nervous
system, ivn-mouse TDLo=3200 ug/kg.
Reproductive Effects:
Anhydrous: see Rtecs# GL8800000:
itt-rat TDLo=3192 ug/kg; testes/sperm duct/epididymis, scu-mouse
TDLo=12768 ug/kg.
Neurotoxicity:
No information available.
Mutagenicity:
See Rtecs# GL8900000.
Other Studies:
None.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Rainbow trout (fresh water) TLm=3.8 ppm/24H
LC50=0.14 ppm/48H
goldfish, eel 0.1-2.5 mg/l
Environmental Fate:
If released to soil, copper sulfate may leach to groundwater, be
partly oxidized, or bind to humic materials, clay, or hydrous of
iron and manganese. In water, it will bind to carbonates as well as
humic materials, clay and hydrous oxides of iron and manganese.
Copper is accumulated by plants and animals, but it does not appear
to biomagnify from plants to animals. This lack of biomagnification
appears common with heavy metals. In air, copper aerosols (in
general) have a residence time of 2 to 10 days in an unpolluted
atmosphere and 0.1 to > 4 days in polluted, urban areas.
Physical/Chemical:
No information available.
Other:
None.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
RCRA D-Series Maximum Concentration of Contaminants:
None listed.
RCRA D-Series Chronic Toxicity Reference Levels: None
listed.
RCRA F-Series: None listed.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Not listed as a material banned from land disposal
according to RCRA.
**** SECTION 14 - TRANSPORT INFORMATION ****
US DOT
Shipping Name: TOXIC SOLID, INORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 3288
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, INORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 3288
Packing Group: III
IATA
Shipping Name: TOXIC SOLID, INORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 3288
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, INORGANIC, N.O.S.
Dangerous Goods Code: 6.1(65C)
UN Number: 3288
Canadian TDG
Shipping Name: CUPRIC SULFATE
Hazard Class: 9.2
UN Number: UN9109
Other Information: REGULATED LIMIT 5 KG
**** SECTION 15 - REGULATORY INFORMATION ****
US FEDERAL
TSCA
CAS# 7758-99-8 is not on the TSCA Inventory. It is a hydrate and
exempt from TSCA Inventory requirements (40CFR270.3(u)(2)).
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
Section 302 (RQ)
None of the chemicals in this material have an RQ.
Section 302 (TPQ)
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 7758-99-8: acute, chronic.
Section 313
This chemical is not at a high enough concentration to be reportable
under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous
Substances under the CWA.
CAS# 7758-99-8 is listed as a Priority Pollutant under the Clean
Water Act.
CAS# 7758-99-8 is listed as a Toxic Pollutant under the Clean Water
Act.
OSHA:
None of the chemicals in this product are considered highly hazardous
by OSHA.
STATE
COPPER(II) SULFATE PENTAHYDRAT can be found on the following state
right to know lists: California, (listed as COPPER), California,
(listed as COPPER COMPOUNDS, N.O.S.), New Jersey, (listed as COPPER),
Florida, (listed as COPPER), Pennsylvania, (listed as COPPER),
Minnesota, (listed as COPPER), Massachusetts, (listed as COPPER).
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/38 Irritating to eyes and skin.
Safety Phrases:
S 22 Do not inhale dust.
WGK (Water Danger/Protection)
CAS# 7758-99-8: 2
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
This product has a WHMIS classification of D1B, D2B.
CAS# 7758-99-8 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 7758-99-8:. OEL-ARAB Republic of Egypt:TWA 0.1 mg(Cu)/m3 (fume)
(dust). OEL-BELGIUM:TWA 0.2 mg(Cu)/m3 (fume). OEL-BELGIUM:TWA 1 mg(Cu
)/m3 (dust). OEL-DENMARK:TWA 0.1 mg(Cu)/m3 (fume). OEL-DENMARK:TWA 1 m
g(Cu)/m3 (dust). OEL-FINLAND:TWA 0.2 mg(Cu)/m3 (fume). OEL-FINLAND:TWA
1 mg(Cu)/m3. OEL-FINLAND:TWA 1 mg(Cu)/m3 (dust). OEL-FRANCE:TWA 0.2 m
g(Cu)/m3 (fume). OEL-FRANCE:TWA 1 mg(Cu)/m3;STEL 2 mg(Cu)/m3 (dust. OE
L-GERMANY:TWA 0.1 mg(Cu)/m3 (fume). OEL-GERMANY:TWA 1 mg(Cu)/m3. OEL-G
ERMANY:TWA 1 mg(Cu)/m3 (dust). OEL-HUNGARY:TWA 0.2 mg(Cu)/m3;STEL 0.4
mg(Cu)/m3 (dust). OEL-INDIA:TWA 0.2 mg(Cu)/m3 (fume). OEL-THE NETHERLA
NDS:TWA 02 mg(Cu)/m3 (fume). OEL-THE NETHERLANDS:TWA 1 mg(Cu)/m3 (dust
). OEL-THE PHILIPPINES:TWA 1.0 mg(Cu)/m3 (fume) JAN9. OEL-POLAND:TWA 0
.1 mg(Cu)/m3 (fume). OEL-RUSSIA:STEL 0.5 ppm (1 mg(Cu)/m3) (dust) JAN9
. OEL-SWEDEN:TWA 0.2 mg(Cu)/m3 (resp. dust). OEL-SWEDEN:TWA 0.2 mg(Cu)
/m3 (fume). OEL-SWEDEN:TWA 1 mg(Cu)/m3 (total dust). OEL-SWITZERLAND:T
WA 0.1 mg(Cu)/m3;STEL 0.2 mg(Cu)/m3 (fume)
u)/m3;STEL 1 mg(Cu)/m3
ILAND:TWA 1 mg(Cu)/m3
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/27/1996 Revision #1 Date: 3/05/1998
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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