UNION CARBIDE -- ETHANOL SDA 3A 200 PROOF - ETHYL ALCOHOL,ABSOLUTE,ACS MATERIAL SAFETY DATA SHEET NSN: 6810002010904 Manufacturer's CAGE: 61637 Part No. Indicator: A Part Number/Trade Name: ETHANOL SDA 3A 200 PROOF =========================================================================== General Information =========================================================================== Item Name: ETHYL ALCOHOL,ABSOLUTE,ACS Company's Name: UNION CARBIDE CORP., INDUSTRIAL CHEMICALS DIVISION Company's Street: 39 OLD RIDGEBURY ROAD Company's City: DANBURY Company's State: CT Company's Country: US Company's Zip Code: 06817-0001 Company's Emerg Ph #: 800-822-4357 Company's Info Ph #: 304-744-3487 Record No. For Safety Entry: 011 Tot Safety Entries This Stk#: 015 Status: SE Date MSDS Prepared: 28SEP90 Safety Data Review Date: 12JUL93 Supply Item Manager: CX MSDS Serial Number: BRDHV Specification Number: O-E-760D Spec Type, Grade, Class: III TYPE Hazard Characteristic Code: F5 Unit Of Issue: DR Unit Of Issue Container Qty: 55 GALLONS Type Of Container: DRUM Net Unit Weight: 361.8 LBS =========================================================================== Ingredients/Identity Information =========================================================================== Proprietary: NO Ingredient: ETHYL ALCOHOL (ETHANOL) Ingredient Sequence Number: 01 Percent: 96.2 NIOSH (RTECS) Number: KQ6300000 CAS Number: 64-17-5 OSHA PEL: 1000 PPM ACGIH TLV: 1000 PPM; 9293 Other Recommended Limit: NONE RECOMMENDED ------------------------------------- Proprietary: NO Ingredient: METHYL ALCOHOL (METHANOL) (SARA III) Ingredient Sequence Number: 02 Percent: 4.7 NIOSH (RTECS) Number: PC1400000 CAS Number: 67-56-1 OSHA PEL: S,200PPM/250STEL ACGIH TLV: S,200PPM/250STEL; 93 Other Recommended Limit: NONE RECOMMENDED ------------------------------------- Proprietary: NO Ingredient: ISOPROPYL ALCOHOL (SARA III) Ingredient Sequence Number: 03 Percent: 25 PPM NIOSH (RTECS) Number: NT8050000 CAS Number: 67-63-0 OSHA PEL: 400 PPM/500 STEL ACGIH TLV: 400 PPM/500STEL;9293 Other Recommended Limit: NONE RECOMMENDED ------------------------------------- Proprietary: NO Ingredient: ACETALDEHYDE (SARA III) Ingredient Sequence Number: 04 Percent: 10 PPM NIOSH (RTECS) Number: AB1925000 CAS Number: 75-07-0 OSHA PEL: 200 PPM/150 STEL ACGIH TLV: C25,A3 93-94 Other Recommended Limit: NONE RECOMMENDED =========================================================================== Physical/Chemical Characteristics =========================================================================== Appearance And Odor: CLEAR, WATER-WHITE LIQUID. CHARACTERISTIC ODOR. Boiling Point: 171F,77C Melting Point: <-148F,<-10 Vapor Pressure (MM Hg/70 F): 48 Vapor Density (Air=1): 1.6 Specific Gravity: 0.791 Decomposition Temperature: UNKNOWN Evaporation Rate And Ref: 3.6 (BUTYL ACETATE = 1) Solubility In Water: COMPLETE Percent Volatiles By Volume: 100 Viscosity: UNKNOWN =========================================================================== Fire and Explosion Hazard Data =========================================================================== Flash Point: 56.0F,13.3C Flash Point Method: TCC Lower Explosive Limit: 3.3(ETHANOL) Upper Explosive Limit: 36(METHANOL) Extinguishing Media: USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Special Fire Fighting Proc: WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire And Expl Hazrds: COMBUSTION OR HEAT OF FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS. VAPORS HEAVIER THAN AIR. CAN TRAVEL ALONG GROUND AND FLASHBACK. =========================================================================== Reactivity Data =========================================================================== Stability: YES Cond To Avoid (Stability): HIGH HEAT, OPEN FLAMES AND OTHER SOURCES OF IGNITION Materials To Avoid: STRONG OXIDIZING AGENTS Hazardous Decomp Products: CARBON MONOXIDE CAN FORM ON INCOMPLETE COMBUSTION. Hazardous Poly Occur: NO Conditions To Avoid (Poly): NOT APPLICABLE =========================================================================== Health Hazard Data =========================================================================== LD50-LC50 Mixture: LD50 (ORAL RAT) IS 7060 MG/KG (ETHANOL) Route Of Entry - Inhalation: YES Route Of Entry - Skin: YES Route Of Entry - Ingestion: YES Health Haz Acute And Chronic: ACUTE: INHALATION:MAY CAUSE HEADACHE, DROWINESS & LASSITUDE, LOSS OF APPETITE & INABILITY TO CONCENTRATE. IRRITATION OF THE THROAT. INGESTION: CAN CAUSE DEPRESSION OF CNS, NAUSEA, VOMITING & DIARRHEA. EYE:LIQUID OR VAPOR MAY CAUSE IRRITATION. SKIN: MAY CAUSE IRRITATION AND DEFATTING OF SKIN ON PROLONGED CONTACT. Carcinogenicity - NTP: NO Carcinogenicity - IARC: NO Carcinogenicity - OSHA: NO Explanation Carcinogenicity: NONE OF THE COMPOUNDS IN THIS PRODUCT IS LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN. Signs/Symptoms Of Overexp: MAY CAUSE EYE, SKIN & RESPIRATORY TRACT IRRITATION. INDIVIDUAL RESPONSES TO METHYL ALCOHOL VARY. INGESTION OF LESS THAN 30 ML HAS BEEN FATAL TO HUMANS. IN GENERAL, A FEW OUNCES MAY CAUSE BLINDNESS AND DEATH; AS LITTLE AS 4 ML MAY BE TOXIC IF INGESTED. MAY CAUSE HEADACHE, DROWINESS, CNS DEPRESSION, NAUSEA, & DIARRHEA. Med Cond Aggravated By Exp: PERSONS WITH A HISTORY OF AILMENTS OR WITH A PRE-EXISTING DISEASE INVOLVING THE SKIN, EYE, RESPIRATORY TRACT, LIVER OR KIDNEY MAY BE AT INCREASED RISK FROM EXPOSURE. Emergency/First Aid Proc: INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING. GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES. GET MEDICAL ATTENTION. SKIN:REMOVE CONTAMINATED CLOTHING. FLUSH WITH WATER. IF IRRITATION PERSISTS, GET MEDICAL ADVICE. INGESTION:DO NOT INDUCE VOMITING UNLESS INSTRUCTED TO DO SO. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE MEDICAL ATTENTION. =========================================================================== Precautions for Safe Handling and Use =========================================================================== Steps If Matl Released/Spill: WEAR APPROPRIATE RESPIRATORY PROTECTION AND PROTECTIVE CLOTHING. CONTAIN SPILLED MATERIAL. TRANSFER TO SECURE CONTAINERS. WHERE NECESSARY, COLLECT USING ABSORBENT MEDIA. ELIMINATE ANY SOURCE OF IGNITION. VENTILATE AREA. WASH RESIDUE WITH WATER. Neutralizing Agent: NOT APPLICABLE. Waste Disposal Method: ALL RECOVERED MATERIAL SHOULD BE PACKAGED, LABELED, TRANSPORTED, AND DISPOSED OR RECLAIMED IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS AND IN CONFORMANCE WITH GOOD ENGINEERING PRACTICES. Precautions-Handling/Storing: STORE IN A FLAMMABLE LIQUID STORAGE ROOM OR CABINET. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. PROTECT CONTAINERS FROM PHYSICAL DAMAGE. Other Precautions: MAKE FREQUENT CAREFUL LEAKAGE INSPECTIONS. ISOLATE FROM OXIDEZERS, CHEMICALS CAPABLE OF SPONTANEOUS HEATING, MATERIALS REACTING WITH AIR OR MOISTURE TO LIBERATE HEAT, IGNITION SOURCES AND EXPLOSIVES. KEEP OUT OF DIRECT SUN & AWAY FROM HEAT. =========================================================================== Control Measures =========================================================================== Respiratory Protection: IF VENTILATION DOES NOT MAINTAIN INHALATION EXPOSURES BELOW PEL(TLV), USE NIOSH/MSHA APPROVED RESPIRATORS. RESPIRATORS SHOULD BE SELECTED BASED ON THE FORM AND CONCENTRATION OF CONTAMINANT IN AIR & IN ACCORDANCE WITH OSHA (29 CFR 1910.134). Ventilation: MECHANICAL (GENERAL) ROOM VENTILATION IS NORMALLY ADEQUATE. LOCAL EXHAUST MAY BE REQUIRED IF WORK AREA NOT VENTED. Protective Gloves: NEOPRENE, NITRILE, VPC OR NATURAL RUBBER Eye Protection: SAFETY GOGGLES WITH OPTIONAL FACE SHIELD Other Protective Equipment: EYE WASH STATION AND SAFETY SHOWER. INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED. Work Hygienic Practices: OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Suppl. Safety & Health Data: AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO NOT BREATHE VAPORS OR MISTS. CAUTION: FOR MANUFACTURING, PROCESSING, REPACKING OR INDUSTRIAL USE. NOT FOR HOUSHOLD USE. CONTAINER HAZARDOUS WHEN EMPTY. EMPTIED CONTAINERS RETAIN RESIDUAL LIQUID AND VAPOR. FOLLOW PRECAUTIONS ON LABEL AND IN MSDS. =========================================================================== Transportation Data =========================================================================== Trans Data Review Date: 93193 DOT PSN Code: EGH DOT Symbol: D DOT Proper Shipping Name: DENATURED ALCOHOL DOT Class: 3 DOT ID Number: NA1986 DOT Pack Group: I DOT Label: FLAMMABLE LIQUID, POISON IMO PSN Code: ANB IMO Proper Shipping Name: ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. o IMO Regulations Page Number: 3176 IMO UN Number: 1986 IMO UN Class: 3.2 IMO Subsidiary Risk Label: TOXIC IATA PSN Code: ARM IATA UN ID Number: 1986 IATA Proper Shipping Name: ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. * IATA UN Class: 3 IATA Subsidiary Risk Class: 6.1 IATA Label: FLAMMABLE LIQUID & TOXIC AFI PSN Code: ARM AFI Symbols: 0 AFI Prop. Shipping Name: ALCOHOLS, TOXIC, N.O.S. AFI Class: 3 AFI ID Number: UN1986 AFI Pack Group: II AFI Label: 6.1 AFI Basic Pac Ref: 7-7 N.O.S. Shipping Name: ETHANOL, METHANOL. =========================================================================== Disposal Data =========================================================================== =========================================================================== Label Data =========================================================================== Label Required: YES Technical Review Date: 12JUL93 Label Status: F Common Name: EHANOL SDA 3A,200 PROOF Signal Word: DANGER! Acute Health Hazard-Severe: X Contact Hazard-Slight: X Fire Hazard-Severe: X Reactivity Hazard-None: X Special Hazard Precautions: ACUTE: INHALATION: MAY CAUSE HEADACHE, DROWINESS & LASSITUDE, LOSS OF APPETITE & INABILITY TO CONCENTRATE. IRRITATION OF THE THROAT. INGESTION: CAN CAUSE DEPRESSION OF CNS, NAUSEA, VOMITING & DIARRHEA. EYES: LIQUID OR VAPOR MAY CAUSE IRRITATION. SKIN: MAY INHALATION: REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING. SEE DOCTOR. EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES. GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. FLUSH WITH WATER. IF IRRITATION PERSISTS, GET MEDICAL ADVICE. INGESTION: DO NOT INDUCE VOMITING. SEE DOCTOR IMMEDIATELY. Protect Eye: Y Protect Skin: Y Label Name: UNION CARBIDE CORP., INDUSTRIAL CHEMICALS DIVISION Label Street: 39 OLD RIDGEBURY ROAD Label City: DANBURY Label State: CT Label Zip Code: 06817-0001 Label Country: US Label Emergency Number: 800-822-4357